Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate
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Authors
Oshin, Kayode
Landis, Arthur M.
Smucker, Bradley W.
Eichhorn, David M.
Rillema, D. Paul
Advisors
Issue Date
2004
Type
Article
Keywords
Organic compounds , Hydrogen bonds
Citation
Oshin, K., Landis, A. M., Smucker, B. W., Eichhorn, D. M. & Rillema, D. P. (2004). fac-BipyridylÂÂtriÂÂcarbonylÂÂ(pyridine)ÂÂrhenium(I) triÂÂfluoroÂÂmethaneÂÂsulfonate. Acta Cryst. E60, m1126â m1127.
Abstract
The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.
Table of Contents
Description
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Publisher
International Union of Crystallography
Journal
Acta Crystallographica Section E: Structure Reports Online
Book Title
Series
PubMed ID
ISSN
16005368