Benzohyroxamic acid and its borate complex
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Authors
Fields, Alan Ray
Advisors
Christian, Robert V.
Issue Date
1962-08
Type
Thesis
Keywords
Citation
Abstract
The purpose of this investigation was to study the borate complex of benzohydroxamic acid. The objectives were 1) to determine the dissociation constants of benzocydroxamic acid and of the borobenzohydroxamic acid complex, 2) to find the ratio of boric acid to benzohydroxamic acid in the complex, and 3) to investigate a possible instability of the complex, as reported by Green(5), at high pH.
Table of Contents
Introduction -- Experimental: A. Apparatus, B. Materials, C. Preparation of samples for ultraviolet and infrared spectrophotometric studies -- Dissoclation constants: A. Potentiometric titrations, Data and results, B., Spectrophotometric studies, data and results -- Nature of the complex: A. A continuous variation study measuring hydrogen ion concentration, data and results, B. Spectrophotometric determination of the composition and acid dissociation constant of the complex, data and results, C. Attempted structural description, data and results, D. Instability of the complex at high pH, data and results -- Discussion and conclusions -- Summary -- Literature cited
Description
Thesis (M.S.)-- University of Wichita, College of Liberal Arts and Sciences, Dept. of Chemistry
Publisher
Wichita State University