Self-assembled single-walled carbon nanotube:zinc-porphyrin hybrids through ammonium ion-crown ether interaction: construction and electron transfer

dc.contributorWichita State University. Department of Chemistryen_US
dc.contributor.authorD'Souza, Francisen_US
dc.contributor.authorChitta, Raghuen_US
dc.contributor.authorSandanayaka, Atula S. D.en_US
dc.contributor.authorSubbaiyan, Navaneetha K.en_US
dc.contributor.authorD'Souza, Lawrenceen_US
dc.contributor.authorAraki, Yasuyakien_US
dc.contributor.authorIto, Osamuen_US
dc.descriptionClick on the DOI link below to access the article (may not be free).en_US
dc.description.abstractAn ammonium ion-crown ether interaction has been successfully used to construct porphyrin-single-walled carbon nanotube (SWNT) donor-acceptor hybrids. The [18]crown-6 to alkyl ammonium ion binding strategy resulted in porphyrin-SWNT nanohybrids that are stable and soluble in DMF. The porphyrin-SWNT hybrids were characterized by spectroscopic, TEM, and electrochemical techniques. Both steady-state and time-resolved emission studies revealed efficient quenching of the singlet excited state of the porphyrins and free-energy calculations suggested that electron-transfer quenching occurred. Nanosecond transient absorption spectral results supported the charge-separation quenching process. Charge-stabilization was also observed for the nanohybrids in which the lifetime of the radical ion pairs was around 100 ns. The present nanohybrids were also used to reduce the hexyl viologen dication (HV2+) and to oxidize 1-benzyl-1,4-dihydronicotinamide in solution in an electron-pooling experiment. Accumulation of the radical cation (HV.+) was observed in high yields, which provided additional proof for the occurrence of photoinduced charge separation. The present study demonstrates that a hydrogen-bonding motif is a successful self-assembly method to build SWNTs bearing donor-acceptor nanohybrids, which are useful for light-energy harvesting and photovoltaic applications.en_US
dc.description.versionpeer revieweden_US
dc.identifier.citationChemistry (Weinheim an der Bergstrasse, Germany). 2007; 13(29): 8277-84.en_US
dc.publisherJohn Wiley and Sonsen_US
dc.relation.ispartofseriesChemistry (Weinheim an der Bergstrasse, Germany)en_US
dc.rights.holderCopyright © 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheimen_US
dc.titleSelf-assembled single-walled carbon nanotube:zinc-porphyrin hybrids through ammonium ion-crown ether interaction: construction and electron transferen_US