Non-aqueous titration of hydroxamic acids

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Issue Date
1966-01-01
Embargo End Date
Authors
Stamey, T. W.
Christian, Robert
Advisor
Citation

Talanta. 1966 Jan; 13(1): 144-51.

Abstract

Benzohydroxamic acid is titrated with 0.1M tetrabutyl-anunonium hydroxide in nine non-aqueous solvents with three different indicating electrodes. The best results are obtained using dimethylformamide as solvent and platinum-platinum electrodes. Four monoprotic and three diprotic hydroxamie acids and iron(III) benzohydroxamate have been successfully titrated with this system. The effect of quantitative additions of carbon dioxide to the titrant on its apparent molarity are found to be dependent on the amount added, the strength and sample size of acid titrated and the solvent used.

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