Supramolecular porphyrin-fullerene via 'two-point' binding strategy: axial-coordination and cation-crown ether complexation

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Issue Date
2005-03-14
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Authors
D'Souza, Francis
Chitta, Raghu
Gadde, Suresh
Zandler, Melvin E.
Sandanayaka, Atula S. D.
Araki, Yasuyaki
Ito, Osamu
Advisor
Citation

Chemical communications (Cambridge, England). 2005 Mar 14; (10): 1279-81.

Abstract

A highly stable porphyrin-fullerene conjugate with defined distance and orientation, was formed using a newly developed 'two-point' binding strategy involving axial-coordination and cation-crown ether complexation; photochemical studies performed in benzonitrile revealed efficient charge separation and slow charge-recombination in the supramolecular complex.

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