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dc.contributor.authorPanja, Anangamohan
dc.contributor.authorMoore, Curtis E.
dc.contributor.authorEichhorn, David M.
dc.date.accessioned2013-09-16T19:46:33Z
dc.date.available2013-09-16T19:46:33Z
dc.date.issued2013-09-10
dc.identifier.citationAnangamohan Panja, Curtis E. Moore, David M. Eichhorn. 2013. A linear S-bridged trinuclear cobalt(III) complex with 2-aminobenzenethiol: synthesis, crystal structure, and spectroscopic characterization. Journal of Coordination Chemistry, v.66:no.17:pp.3037-3044, 2013en_US
dc.identifier.issn0095-8972
dc.identifier.otherWOS:000323312600008
dc.identifier.urihttp://dx.doi.org/10.1080/00958972.2013.823486
dc.identifier.urihttp://hdl.handle.net/10057/6492
dc.descriptionClick on the DOI link to access the article (may not be free).en_US
dc.description.abstractTreatment of cobalt(II) perchlorate hexahydrate with 2 M equiv. of 2-aminobenzenethiol (Habt) in acetonitrile afforded a tricationic tricobalt complex, [Co{Co(abt)3}2](ClO4)3·2CH3CN, by aerial oxidation. The molecular structure of the meso (ΔΛ) form of the complex was determined by X-ray crystallography. In the complex cation, the central Co is coordinated by six thiolate groups from two terminal fac(S)-[Co(abt)3] units in an octahedral geometry, forming a linear S-bridged tricobalt structure.en_US
dc.description.sponsorshipUniversity Grants Commission, India (Sanction No. PSW-173/11-12). D. M. E. acknowledges support from the National Center for Research Resources - NIH COBRE Award P20 RR017708.en_US
dc.language.isoen_USen_US
dc.publisherTaylor & Francisen_US
dc.relation.ispartofseriesJournal of Coordination Chemistry;v.66:no.17
dc.subjectTrinuclear S-bridged linear Co(III) complexen_US
dc.subject2-Aminobenzenethiolen_US
dc.subjectCrystal structure of the meso isomeren_US
dc.subjectSpectral propertiesen_US
dc.titleA linear S-bridged trinuclear cobalt(III) complex with 2-aminobenzenethiol: synthesis, crystal structure, and spectroscopic characterizationen_US
dc.typeArticleen_US
dc.description.versionPeer reviewed


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