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    A linear S-bridged trinuclear cobalt(III) complex with 2-aminobenzenethiol: synthesis, crystal structure, and spectroscopic characterization

    Date
    2013-09-10
    Author
    Panja, Anangamohan
    Moore, Curtis E.
    Eichhorn, David M.
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    Citation
    Anangamohan Panja, Curtis E. Moore, David M. Eichhorn. 2013. A linear S-bridged trinuclear cobalt(III) complex with 2-aminobenzenethiol: synthesis, crystal structure, and spectroscopic characterization. Journal of Coordination Chemistry, v.66:no.17:pp.3037-3044, 2013
    Abstract
    Treatment of cobalt(II) perchlorate hexahydrate with 2 M equiv. of 2-aminobenzenethiol (Habt) in acetonitrile afforded a tricationic tricobalt complex, [Co{Co(abt)3}2](ClO4)3·2CH3CN, by aerial oxidation. The molecular structure of the meso (ΔΛ) form of the complex was determined by X-ray crystallography. In the complex cation, the central Co is coordinated by six thiolate groups from two terminal fac(S)-[Co(abt)3] units in an octahedral geometry, forming a linear S-bridged tricobalt structure.
    Description
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    URI
    http://dx.doi.org/10.1080/00958972.2013.823486
    http://hdl.handle.net/10057/6492
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