Show simple item record

dc.contributor.authorRillema, D. Paul
dc.contributor.authorCruz, Arvin John Filoteo
dc.contributor.authorTasset, Brandon J.
dc.contributor.authorMoore, Curtis E.
dc.contributor.authorSiam, Khamis
dc.contributor.authorHuang, Wei
dc.date.accessioned2013-06-28T14:43:07Z
dc.date.available2013-06-28T14:43:07Z
dc.date.issued2013-06-10
dc.identifier.citationRillema, D. Paul; Cruz, Arvin John Filoteo; Tasset, Brandon J.; Moore, Curtis E.; Siam, Khamis; Huang, Wei. 2013. Structural properties of platinum(II) biphenyl complexes containing 1,10-phenanthroline derivatives. Volume 1041, 10 June 2013, Pages 82–91en_US
dc.identifier.issn0022-2860
dc.identifier.otherWOS:000319176700013
dc.identifier.urihttp://dx.doi.org/10.1016/j.molstruc.2013.03.006
dc.identifier.urihttp://hdl.handle.net/10057/5822
dc.descriptionClick on the DOI link to access the article (may not be free).en_US
dc.description.abstractSeven platinum(II) complexes formulated as Pt(bph)L, where bph is the 2,2'-biphenyl dianion and L = 4-methyl-1,10-phenanthroline (4-Mephen), 5-methyl-1,10-phenanthroline (5-Mephen), 5-chloro-1,10-phenanthroline (5-Clphen), 5,6-dimethyl-1,10-phenanthroline (5,6-Me(2)phen), 4,7-dimethyl-1,10-phenanthroline (4,7-Me(2)phen), 4,7-diphenyl-1,10-phenanthroline (4,7-Ph(2)phen) and 3,4,7,8-tetra-methyl-1,10-phenanthroline (3,4,7,8-Me(4)phen) are reported. Protons attached to the phen ligand resonate downfield from those attached to the bph ligand and two proton signals are split by interaction with Pt-195. Pt(bph)(3,4,7,8-Me(4)phen), Pt(bph)(4,7-Me(2)phen), Pt(bph)(5,6-Me(2)phen), Pt(bph)(4,7-Ph(2)phen) and Pt(bph)(5-Mephen) crystallize in the space groups Pna2(1), P2(1)/n, P2(1)/c, P - 1 and Pca2(1), respectively. The structures of the complexes deviate from true planarity and divide themselves into two groups where the bph and phen ligands cross in an X configuration or bow out in a butterfly (B) configuration. Circular dichroism revealed two different spectra with respect to the X and B configurations. (C) 2013 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipNational Science Foundation (EPSCoR); Wichita State University Office of Research Administration; Department of Energen_US
dc.language.isoen_USen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofseriesJournal of Molecular Structure;v.1041
dc.subjectPlatinum (II)en_US
dc.subjectBiphenyl dianionen_US
dc.subjectPhenanthrolineen_US
dc.subjectX-rayen_US
dc.subjectH-1 NMRen_US
dc.subjectCDen_US
dc.subjectDensity-functional theoryen_US
dc.subjectTransition-metal-complexesen_US
dc.subjectCircular-dichroism spectraen_US
dc.subjectPhotophysical propertiesen_US
dc.subjectBasis-setsen_US
dc.subjectSolid-stateen_US
dc.subjectExcitation-energiesen_US
dc.subjectCrystal-structureen_US
dc.subjectLigandsen_US
dc.subjectPotentialsen_US
dc.titleStructural properties of platinum(II) biphenyl complexes containing 1,10-phenanthroline derivativesen_US
dc.typeArticleen_US
dc.description.versionPeer reviewed
dc.rights.holderCopyright © 2013, Elsevier


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record