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dc.contributor.authorChen, Y.Y.
dc.contributor.authorWoods, Clifton
dc.contributor.authorPerkovic, Marc W.
dc.contributor.authorRillema, D. Paul
dc.date.accessioned2013-06-17T19:01:22Z
dc.date.available2013-06-17T19:01:22Z
dc.date.issued1996-08
dc.identifier.citationChen, Y.; Woods, Clifton; Perkovic, Marc W.; Rillema, D. Paul. 1996. Crystal structure, physical and photophysical properties of a platinum(II) complex coordinated to the biphenyl dianion and cyclooctadiene. Journal of Chemical Crystallography, v.26 no.8 pp.527-531en_US
dc.identifier.issn1572-8854
dc.identifier.urihttp://dx.doi.org/10.1007/BF01668410
dc.identifier.urihttp://hdl.handle.net/10057/5722
dc.descriptionClick on the DOI link to access the article (may not be free).en_US
dc.description.abstractThe complex, Pt(bph)(COD), where bph is the biphenyl dianion and COD is 1,5-cyclooctadiene, crystallizes in the orthorhombic space groupPbca witha=12.178(4) Å,b=9.693(3) Å andc=25.344(9) Å andZ=8. The Pt−C distances to the olefinic carbon atoms that result from the π electron donation of the COD ligand are in the range 2.20(3)−2.27(3) Å and the Pt−C distances to the σ bonded bph ligand are shorter at 2.01(3)−2.03(2) Å. The lowest energy absorption of the complex is at 383 nm (ε=1.2×103). The emission spectrum is structured in fluid solution at room temperature with the emission energy maximum at 537 nm, φcm, and τ=1.93 μs. Temperature dependent emission lifetime measurements result in ak o value of 2.69×104, a preexponential factor of 2.47×106 and a ΔE1 value of 324 cm−1.en_US
dc.language.isoen_USen_US
dc.publisherKluwer Academic Publishers-Plenum Publishersen_US
dc.relation.ispartofseriesJournal of Chemical Crystallography;v.26 no.8
dc.subjectPlatinum(II) moleculesen_US
dc.subjectbiphenyl dianionen_US
dc.subjectcyclooctadieneen_US
dc.titleCrystal structure, physical and photophysical properties of a platinum(II) complex coordinated to the biphenyl dianion and cyclooctadieneen_US
dc.typeArticleen_US
dc.description.versionPeer reviewed
dc.rights.holderCopyright © 1996, Plenum Publishing Corporation


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