Show simple item record

dc.contributor.authorJohnson, Donald M.
dc.contributor.authorEichhorn, David M.
dc.contributor.authorMoore, Curtis E.
dc.contributor.authorMwania, Tom M.
dc.contributor.authorZhao, Ningfeng
dc.date.accessioned2012-07-19T15:16:23Z
dc.date.available2012-07-19T15:16:23Z
dc.date.issued2012-07
dc.identifier.citationJohnson, Donald M.; Eichhorn, David M.; Moore, Curtis E.; Mwania, Tom M. & Ningfeng, Zhao. 2012. Thallium(I) Complexes of Cyano-Substituted Bispyrazolylborate Ligands, JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, Volume 42, Number 7 (2012), 746-751, DOI: 10.1007/s10870-012-0310-0en_US
dc.identifier.issn1074-1542
dc.identifier.issn1572-8854
dc.identifier.otherWOS: 000305563100016
dc.identifier.urihttp://hdl.handle.net/10057/5243
dc.identifier.urihttp://dx.doi.org/10.1007/s10870-012-0310-0
dc.descriptionClick on the DOI link below to access the article (may not be free).en_US
dc.description.abstractTwo thallium scorpionate complexes: dihydrobis(3-phenyl-4-cyanopyrazolyl)boratothallium(I) (TlBp(Ph,4CN)), C20H14BN6Tl and dihydrobis(3-tert-butyl-4-cyanopyrazolyl)boratothallium(I) (TlBp (t-Bu,4CN)), C16H22BN6Tl have been prepared and characterized by X-ray diffraction. Both compounds crystallize in monoclinic space groups, TlBp(Ph,4CN) in P2(1)/n with a = 4.2039(3) , b = 26.2211(17) , c = 16.611(1) , beta = 90.199(3)A degrees, and TlBp (t-Bu,4CN) in P2(1)/c with a = 13.8578(5) , b = 9.6741(4) , c = 14.2790(5) , beta = 95.141(2)A degrees. The two complexes show similar structures with elongated metal-ligand bonds and intermolecular interactions between the metal ion and cyano substituents, allowing the potential construction of cyano-bridged coordination polymers.en_US
dc.description.sponsorshipThe authors thank Drs. Reza Mohseni and John Hyatt from the Department of Chemistry, East Tennessee State University (ETSU) for helpful advice on ligands syntheses, and ETSU for financial support. Special thanks go to the reviewers of the paper who brought in helpful comments.en_US
dc.language.isoen_USen_US
dc.publisherSpringeren_US
dc.relation.ispartofseriesJOURNAL OF CHEMICAL CRYSTALLOGRAPHY;2012, Vol.42, No.7
dc.subjectPolypyrazolylborateen_US
dc.subjectThalliumen_US
dc.subjectCyano substituteen_US
dc.subjectWeak interactionsen_US
dc.subject.classificationCRYSTALLOGRAPHY
dc.subject.classificationCRYSTALLOGRAPHY
dc.subject.classificationSPECTROSCOPY
dc.subject.classificationSPECTROSCOPY
dc.titleThallium(I) complexes of cyano-substituted bispyrazolylborate ligandsen_US
dc.typeArticleen_US
dc.description.versionPeer reviewed
dc.rights.holderCopyright © 2012, Springer Science+Business Media, LLC


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record