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dc.contributor.authorRutkowski, Philip X.
dc.contributor.authorRios, Daniel
dc.contributor.authorGibson, John K.
dc.contributor.authorVan Stipdonk, Michael J.
dc.date.accessioned2012-06-19T20:00:48Z
dc.date.available2012-06-19T20:00:48Z
dc.date.issued2011-11
dc.identifier.citationRutkowski, Philip X.; Rios, Daniel; Gibson, John K. and Michael J., Van Stipdonk. 2011. Gas-phase coordination complexes of (UO22+)-O-VI, (NpO22+)-O-VI, and (PuO22+)-O-VI with dimethylformamide. Journal of the American Society for Mass Spectrometry, 22 (11):2042-2048.en_US
dc.identifier.issn1044-0305
dc.identifier.issn1879-1123
dc.identifier.urihttp://hdl.handle.net/10057/5172
dc.identifier.urihttp://dx.doi.org/10.1007/s13361-011-0226-5
dc.descriptionClick on the DOI link below to access the article (may not be free).en_US
dc.description.abstractElectrospray ionization of actinyl perchlorate solutions in H2O with 5% by volume of dimethylformamide (DMF) produced the isolatable gas-phase complexes, [An(VI)O(2)(DMF)(3)(H2O)](2+) and [An(VI)O(2)(DMF)(4)](2+), where An = U, Np, and Pu. Collision-induced dissociation confirmed the composition of the dipositive coordination complexes, and produced doubly-and singly-charged fragment ions. The fragmentation products reveal differences in underlying chemistries of uranyl, neptunyl, and plutonyl, including the lower stability of Np(VI) and Pu(VI) compared with U(VI).en_US
dc.language.isoen_USen_US
dc.publisherSpringeren_US
dc.relation.ispartofseriesJournal of the American Society for Mass Spectrometry;2011:, v.22, no.11
dc.subjectNeptunylen_US
dc.subjectPlutonylen_US
dc.subjectUranylen_US
dc.subjectActinideen_US
dc.subjectNeptuniumen_US
dc.subjectPlutoniumen_US
dc.subjectUraniumen_US
dc.subjectInorganicen_US
dc.subjectElectrosprayen_US
dc.subjectCollision induced dissociationen_US
dc.titleGas-phase coordination complexes of (UO22+)-O-VI, (NpO22+)-O-VI, and (PuO22+)-O-VI with dimethylformamideen_US
dc.typeArticleen_US
dc.description.versionPeer reviewed
dc.rights.holderCopyright © 2011, American Society for Mass Spectrometry


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