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    Iron and cobalt complexes of 2,6-Diacetylpyridine-bis(R-thiosemicarbazone) (R=H, phenyl) showing unprecedented ligand deviation from planarity

    Date
    2009-03-02
    Author
    Panja, Anangamohan
    Campana, Charles
    Leavitt, Christopher M.
    Van Stipdonk, Michael J.
    Eichhorn, David M.
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    Citation
    Inorganica chimica acta. 2009Mar2; 362(4): 1348-1354.
    Abstract
    The syntheses, characterization, and single-crystal X-ray crystal structures are reported for four complexes of iron and cobalt with the pentadentate ligands, 2,6-diacetylpyridinebis(thiosemicarbazone) (H(2)L(1)) and 2,6-diacetylpyridinebis-(phenylthiosemicarbazone) (H(2)L(2)), including a cobalt dimer displaying a deviation from planarity which is unprecedented for this class of ligands and allows the ligand to occupy five positions of a pseudo-octahedral coordination sphere. This dimer reacts with KCN to produce a mononuclear complex of relevance to the active site of cobalt nitrile hydratase.
    Description
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    URI
    http://dx.doi.org/10.1016/j.ica.2008.06.031
    http://hdl.handle.net/10057/4402
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