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dc.contributorWichita State University. Department of Chemistryen_US
dc.contributor.authorFord, Warren T.en_US
dc.contributor.authorNishioka, Takuyaen_US
dc.contributor.authorQiu, Fengen_US
dc.contributor.authorD'Souza, Francisen_US
dc.contributor.authorChoi, Jai-pilen_US
dc.date.accessioned2012-02-06T17:17:06Z
dc.date.available2012-02-06T17:17:06Z
dc.date.issued2000-09-08en_US
dc.identifier10970324en_US
dc.identifier2985193Ren_US
dc.identifierjo000686den_US
dc.identifier.citationThe Journal of organic chemistry. 2000 Sep 8; 65(18): 5780-4.en_US
dc.identifier.issn1520-6904en_US
dc.identifier.issn0022-3263en_US
dc.identifier.urihttp://hdl.handle.net/10057/4394
dc.descriptionFull text of this article is not available in SOAR.en_US
dc.description.abstractThermal decomposition of dimethyl azo(bisisobutyrate) in a solution containing C(60) produced 1,4- and 1, 16-di(2-carbomethoxy-2-propyl)-1,x-dihydro[60]fullerenes in yields of 21% and 27%, respectively, based on reacted C(60). The structure of this first 1,16-dialkyl-1,16-dihydro[60]fullerene was assigned from (13)C 2D INADEQUATE NMR spectra. The 1,16-isomer has first and second electrochemical reduction potentials shifted positively by 0. 18 V relative to those of the 1,4-isomer. From the close similarity of all spectral, chromatographic, and electrochemical data, the previously unassigned isomer of 1,x-di(2-cyano-2-propyl)-1, x-dihydro[60]fullerene, which was obtained from azo(bisisobutyronitrile) and C(60), is also a 1,16-isomer.en_US
dc.format.extent5780-4en_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.ispartofseriesThe Journal of organic chemistryen_US
dc.relation.ispartofseriesJ. Org. Chem.en_US
dc.sourceNLMen_US
dc.titleDimethyl azo(bisisobutyrate) and C(60) produce 1,4- and 1, 16-Di(2-carbomethoxy-2-propyl)-1,x-dihydroen_US
dc.typeArticleen_US
dc.coverage.spacialUnited Statesen_US
dc.description.versionpeer revieweden_US
dc.rights.holderCopyright © 2000 American Chemical Societyen_US


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