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dc.contributorWichita State University. Department of Chemistryen_US
dc.contributor.authorDeviprasad, Gollapalli R.en_US
dc.contributor.authorSmith, Phillip M.en_US
dc.contributor.authorZandler, Melvin E.en_US
dc.contributor.authorRogers, Lisa M.en_US
dc.contributor.authorD'Souza, Francisen_US
dc.date.accessioned2012-02-06T17:15:56Z
dc.date.available2012-02-06T17:15:56Z
dc.date.issued2006-01-01en_US
dc.identifier16404521en_US
dc.identifier100954728en_US
dc.identifierGM 59038en_US
dc.identifier.citationPhotosynthesis research. 2006 Jan; 87(1): 105-14.en_US
dc.identifier.issn0166-8595en_US
dc.identifier.urihttp://dx.doi.org/10.1007/s11120-005-5450-zen_US
dc.identifier.urihttp://hdl.handle.net/10057/4282
dc.descriptionClick on the DOI link below to access the article (may not be free).en_US
dc.description.abstractFullerene, C(60) was functionalized to possess one or two fluorophore entities. The fluorophore-fullerene dyads thus synthesized contain either a naphthalene, pyrene, or fluorene entity while the triads contain either a pyrene or fluorene entity in addition to a naphthalene entity. The redox behavior of these dyads and triads were probed by cyclic voltammetric technique, while the geometry and electronic structures were deduced from ab initio B3LYP/3-21G(*) method. Steady-state emission studies revealed the occurrence of energy transfer from the singlet excited fluorophore to the fullerene entity in the case of the dyads while the occurrence of step-by-step sequential energy transfer is envisioned in the case of the triads. A better 'antenna-effect' owing to the extended range of excitation wavelength to induce energy transfer to the appended fullerene has been achieved in the case of the triads.en_US
dc.description.sponsorshipNIGMS NIH HHSen_US
dc.format.extent105-14en_US
dc.language.isoengen_US
dc.publisherSpringeren_US
dc.relation.ispartofseriesPhotosynthesis researchen_US
dc.relation.ispartofseriesPhotosyn. Res.en_US
dc.sourceNLMen_US
dc.subjectResearch Support, N.I.H., Extramuralen_US
dc.subject.meshComputational Biologyen_US
dc.subject.meshElectrochemistryen_US
dc.subject.meshElectronsen_US
dc.subject.meshFluorescent Dyes/chemistryen_US
dc.subject.meshFullerenes/chemistryen_US
dc.subject.meshMolecular Structureen_US
dc.titleFluorophore(s) appended fullerene dyads and triads for probing photoinduced energy transfer: syntheses, electronic structure, and fluorescence studiesen_US
dc.typeArticleen_US
dc.coverage.spacialNetherlandsen_US
dc.description.versionpeer revieweden_US
dc.rights.holderCopyright © 2006, Springer Netherlandsen_US


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