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    Initial structural studies of charged receptors that bind to inorganic phosphate anion and to an anionic phospholipid found in bacterial membranes

    Date
    2011-03-18
    Author
    Koralegedara, Manjula B.
    Aw, Hong Wai
    Burns, Dennis H.
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    Citation
    The Journal of organic chemistry. 2011 Mar 18; 76(6): 1930-3.
    Abstract
    ITC titration studies of a family of bis-ammonium receptors based upon a scaffold of two bis-linked phenol rings show that several of the receptors bind to both dihydrogenphosphate and phosphatidylglycerol anions in a similar binding motif. Thermodynamic properties determined from ITC show that anion binding is entropy driven. Job plots determined from (1)H NMR clearly demonstrate that anion-receptor binding stoichiometry is dependent on the receptor's length of its bis-amine linkage.
    Description
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    URI
    http://dx.doi.org/10.1021/jo102383j
    http://hdl.handle.net/10057/4252
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