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dc.contributorWichita State University. Department of Chemistryen_US
dc.contributor.authorCasalboni, Fiorellaen_US
dc.contributor.authorMulazzani, Quinto G.en_US
dc.contributor.authorClark, Catherine D.en_US
dc.contributor.authorHoffman, Morton Z.en_US
dc.contributor.authorOrizondo, Peter L.en_US
dc.contributor.authorPerkovic, Marc W.en_US
dc.contributor.authorRillema, D. Paulen_US
dc.date.accessioned2012-02-06T17:15:38Z
dc.date.available2012-02-06T17:15:38Z
dc.date.issued1997-05-21en_US
dc.identifier11669858en_US
dc.identifier0366543en_US
dc.identifieric960657een_US
dc.identifier.citationInorganic chemistry. 1997 May 21; 36(11): 2252-2257.en_US
dc.identifier.issn1520-510Xen_US
dc.identifier.issn0020-1669en_US
dc.identifier.urihttp://hdl.handle.net/10057/4245
dc.identifier.urihttp://dx.doi.org/10.1021/ic960657e
dc.descriptionClick on the DOI link to access the article (may not be free)en_US
dc.description.abstractThe acid-base and electrochemical properties of the MLCT excited states and the one-electron-reduced forms of the three Ru(bpy)(3)(-)()(p)()(pypm)(p)()(2+) complexes, where bpy = 2,2'-bipyridine, pypm = 2-(2'-pyridyl)pyrimidine, and p = 1-3, have been examined in aqueous solution; a determination has been made of the ground- and excited-state electrochemical potentials, the values of the pK(a) and deprotonation rate constants of the conjugate acids of the excited states and the one-electron-reduced complexes, and the kinetics of the second-order decays of the reduced species. Comparison is made with the behavior of the analogous 10 complexes of the form Ru(bpy)(3)(-)()(m)()(-)()(z)()(bpm)(m)()(bpz)(z)()(2+), where bpm = 2,2'-bipyrimidine, bpz = 2,2'-bipyrazine, m and z = 0-3, and m + z </= 3, which have been studied in detail before.en_US
dc.format.extent2252-2257en_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.ispartofseriesInorganic chemistryen_US
dc.relation.ispartofseriesInorg Chemen_US
dc.sourceNLMen_US
dc.titleAcid-Base and Electrochemical Properties of the MLCT Excited States and One-Electron-Reduced Forms of Ruthenium(II) Complexes Containing 2-(2'-Pyridyl)pyrimidine and 2,2'-Bipyridine in Aqueous Solutionen_US
dc.typeArticleen_US
dc.description.versionpeer revieweden_US
dc.rights.holderCopyright © 1997 American Chemical Societyen_US


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