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dc.contributorWichita State University. Department of Chemistryen_US
dc.contributor.authorVan Stipdonk, Michael J.en_US
dc.contributor.authorChien, Winnieen_US
dc.contributor.authorBulleigh, Kellisen_US
dc.contributor.authorWu, Qunen_US
dc.contributor.authorGroenewold, Gary S.en_US
dc.date.accessioned2012-02-06T17:15:24Z
dc.date.available2012-02-06T17:15:24Z
dc.date.issued2006-01-26en_US
dc.identifier16419996.0en_US
dc.identifier9890903en_US
dc.identifier.citationThe journal of physical chemistry. A. 2006 Jan 26; 110(3): 959-70.en_US
dc.identifier.issn1089-5639en_US
dc.identifier.urihttp://dx.doi.org/10.1021/jp054422cen_US
dc.identifier.urihttp://hdl.handle.net/10057/4235
dc.descriptionClick on the DOI link below to access the article (may not be free).en_US
dc.description.abstractElectrospray ionization was used to generate doubly charged complex ions composed of the uranyl ion and nitrile ligands. The complexes, with general formula [UO2(RCN)n]2+, n = 0-5 (where R=CH3-, CH3CH2-, or C6H5-), were isolated in an ion-trap mass spectrometer to probe intrinsic reactions with H2O. For these complexes, two general reaction pathways were observed: (a) the direct addition of one or more H2O ligands to the doubly charged complexes and (b) charge-reduction reactions. For the latter, the reactions produced uranyl hydroxide, [UO2OH], complexes via collisions with gas-phase H2O molecules and the elimination of protonated nitrile ligands.en_US
dc.format.extent959-70en_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.ispartofseriesThe journal of physical chemistry. Aen_US
dc.relation.ispartofseriesJ Phys Chem Aen_US
dc.sourceNLMen_US
dc.titleGas-phase uranyl-nitrile complex ionsen_US
dc.typeArticleen_US
dc.coverage.spacialUnited Statesen_US
dc.description.versionpeer revieweden_US
dc.rights.holderCopyright © 2006 American Chemical Societyen_US


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