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    Gas-phase uranyl-nitrile complex ions

    Date
    2006-01-26
    Author
    Van Stipdonk, Michael J.
    Chien, Winnie
    Bulleigh, Kellis
    Wu, Qun
    Groenewold, Gary S.
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    Citation
    The journal of physical chemistry. A. 2006 Jan 26; 110(3): 959-70.
    Abstract
    Electrospray ionization was used to generate doubly charged complex ions composed of the uranyl ion and nitrile ligands. The complexes, with general formula [UO2(RCN)n]2+, n = 0-5 (where R=CH3-, CH3CH2-, or C6H5-), were isolated in an ion-trap mass spectrometer to probe intrinsic reactions with H2O. For these complexes, two general reaction pathways were observed: (a) the direct addition of one or more H2O ligands to the doubly charged complexes and (b) charge-reduction reactions. For the latter, the reactions produced uranyl hydroxide, [UO2OH], complexes via collisions with gas-phase H2O molecules and the elimination of protonated nitrile ligands.
    Description
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    URI
    http://dx.doi.org/10.1021/jp054422c
    http://hdl.handle.net/10057/4235
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