Browsing CHEM Faculty Scholarship by Subject "Macromolecular Substances/chemistry"
Now showing items 1-5 of 5
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Design and studies on supramolecular ferrocene-porphyrin-fullerene constructs for generating long-lived charge separated states
(American Chemical Society, 2006-12-21)Supramolecular ferrocene-porphyrin-fullerene constructs, in which covalently linked ferrocene-porphyrin-crown ether compounds were self-assembled with alkylammonium cation functionalized fullerenes, have been designed to ... -
Photosynthetic antenna-reaction center mimicry: sequential energy- and electron transfer in a self-assembled supramolecular triad composed of boron dipyrrin, zinc porphyrin and fullerene
(American Chemical Society, 2009-07-30)A self-assembled supramolecular triad, a model to mimic the photochemical events of photosynthetic antenna-reaction center, viz., sequential energy and electron transfer, has been newly constructed and studied. Boron ... -
Photosynthetic reaction center mimicry of a "special pair" dimer linked to electron acceptors by a supramolecular approach: self-assembled cofacial zinc porphyrin dimer complexed with fullerene(s)
(John Wiley and Sons, 2007-01-01)Biomimetic bacterial photosynthetic reaction center complexes have been constructed using well-defined self-assembled supramolecular approaches. The "special pair" donor, a cofacial porphyrin dimer, was formed via potassium ... -
Supramolecular porphyrin-fullerene via 'two-point' binding strategy: axial-coordination and cation-crown ether complexation
(Royal Society of Chemistry, 2005-03-14)A highly stable porphyrin-fullerene conjugate with defined distance and orientation, was formed using a newly developed 'two-point' binding strategy involving axial-coordination and cation-crown ether complexation; ... -
Supramolecular triad and pentad composed of zinc-porphyrin(s), oxoporphyrinogen, and fullerene(s): design and electron-transfer studies
(John Wiley and Sons, 2007-01-01)By adopting a "covalent-coordinate" bonding approach, novel supramolecular pentad and triad molecules composed of zinc-porphyrin(s), fullerene(s), and oxoporphyrinogen redox-/photoactive entities have been constructed, and ...