Now showing items 1-3 of 3

• #### A$_2$P$_2$S$_6$ (A = Ba and Pb): a good platform to study the polymorph effect and lone pair effect to form an acentric structure ﻿

(The Royal Society of Chemistry, 2022-05-14)
Three ternary thiophosphates α-Ba$_2$P$_2$S$_6$, β-Ba$_2$P$_2$S$_6$, and Pb$_2$P$_2$S$_6$ were synthesized via a high temperature salt flux method or an I2 transport reaction. β-Ba$_2$P$_2$S$_6$ and Pb$_2$P$_2$S$_6$ were ...
• #### Evolution of structure and transport properties of the Ba$_8$Cu$_{16}$P$_{30}$ clathrate-I framework with the introduction of Ga ﻿

(American Institute of Physics Inc., 2022-05-09)
Two type-I clathrates were synthesized by introducing Ga into the framework of the Ba$_8$Cu$_{16}$P$_{30}$ type-I clathrate. The introduction of minute amounts of Ga, 1.9% Ga/Mtotal (where $M_{total}$ = Cu + Ga), resulted ...
• #### Synthesis, crystal growth, electronic properties and optical properties of $Y_6IV_{2.5}S_{14}$ (IV=Si, Ge) ﻿

(Wiley, 2021-12-06)
Two isostructural ternary acentric sulfides, $Y_6Si_{2.5}S_{14}$ (1) and $Y_6Ge_{2.5}S_{14}$ (2) were re-investigated to understand the origin of the chemical flexibility of $RE_6B_xC_yCh_{14}$(RE=Y, La−Lu; B=Si, Ge, Sn, ...