Browsing CHEM Faculty Scholarship by Author "Gibson, John K."

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Electron transfer dissociation of dipositive uranyl and plutonyl coordination complexes

Rios, Daniel; Rutkowski, Philip X.; Shuh, David K.; Bray, Travis H.; Gibson, John K.; Van Stipdonk, Michael J. (John Wiley and Sons, 2011-12)

Reported here is a comparison of electron transfer dissociation (ETD) and collision-induced dissociation (CID) of solvent-coordinated dipositive uranyl and plutonyl ions generated by electrospray ionization. Fundamental ...
Gas-phase coordination complexes of (UO22+)-O-VI, (NpO22+)-O-VI, and (PuO22+)-O-VI with dimethylformamide

Rutkowski, Philip X.; Rios, Daniel; Gibson, John K.; Van Stipdonk, Michael J. (Springer, 2011-11)

Electrospray ionization of actinyl perchlorate solutions in H2O with 5% by volume of dimethylformamide (DMF) produced the isolatable gas-phase complexes, [An(VI)O(2)(DMF)(3)(H2O)](2+) and [An(VI)O(2)(DMF)(4)](2+), where ...