Browsing CHEM Faculty Scholarship by Author "Campana, Charles"
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Iron and cobalt complexes of 2,6-Diacetylpyridine-bis(R-thiosemicarbazone) (R=H, phenyl) showing unprecedented ligand deviation from planarity
Panja, Anangamohan; Campana, Charles; Leavitt, Christopher M.; Van Stipdonk, Michael J.; Eichhorn, David M. (Elsevier, 2009-03-02)The syntheses, characterization, and single-crystal X-ray crystal structures are reported for four complexes of iron and cobalt with the pentadentate ligands, 2,6-diacetylpyridinebis(thiosemicarbazone) (H(2)L(1)) and ... -
Sandwich compounds of cyanotrispyrazolylborates: complexation-induced ligand isomerization
Zhao, Ningfeng; Van Stipdonk, Michael J.; Bauer, Cary; Campana, Charles; Eichhorn, David M. (American Chemical Society, 2007-10-15)Reaction of the new cyanoscorpionate ligand, hydrotris(4-cyano-3-phenyl)pyrazolylborate (Tp(Ph),(4CN)) with Co(II), Mn(II), and Fe(II) unexpectedly results in the isolation only of crystals containing sandwich complexes ...