Browsing CHEM Faculty Scholarship by Title
Now showing items 444-463 of 496
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Syntheses, electrochemistry, and photodynamics of ferrocene-azadipyrromethane donor--acceptor dyads and triads
(American Chemical Society, 2011-09-08)A near-IR-emitting sensitizer, boron-chelated tetraarylazadipyrromethane, has been utilized as an electron acceptor to synthesize a series of dyads and triads linked with a well-known electron donor, ferrocene. The structural ... -
Synthesis and characterization of 2-(2-pyridinyl)pyrazine and 2,2′-bipyrazine derivatives
(Journal of Heterocyclic Chemistry, 2019-01-29)A convenient and high yield preparation of derivatives of 2-(2-pyridinyl)pyrazine and derivatives of 2,2′-bipyrazine compounds from their derivatives of bromopyrazine using Stille coupling is reported. X-ray structures, ... -
Synthesis and characterization of picket porphyrin receptors that bind phosphatidylglycerol, an anionic phospholipid found in bacterial membranes
(American Chemical Society, 2013-01-18)The lipid binding ability of four urea-picket porphyrins designed to bind to both the phosphate anion portion as well as the glycerol hydroxyl groups of phosphatidylglycerol (PG) has been investigated. Isothermal titration ... -
Synthesis and characterization of rhenium(I) 4,4′-dicarboxy-2,2′-bipyridine tricarbonyl complexes for solar energy conversion
(Elsevier, 2020-10-01)The synthesis of a series of rhenium(I) tricarbonyl complexes containing 4,4′-dicarboxy-2,2′-bipyridine (dcbpy) and various halide or pseudohalide ligands is reported. Deprotonation of the carboxylates occurs in basic ... -
Synthesis and computational and experimental investigations of a para-nicotinic acid-bridged dirhenium(I) dimer complex
(American Chemical Society, 2020-05-22)The Re(I) dimer complex, [fac(CO)3(phen)Re1-N(py)COORe2(phen)fac(CO)3]+ (py = pyridine; phen = 1,10-phenanthroline), contains two different Re(I) centers 9.3 Å apart, one with a nitrogen donor and the other with an acetate ... -
Synthesis and luminescence properties of a nonsymmetrical ligand-bridged reI−reI chromophore
(ACS Publications, 2000-09-15)The preparation and the physical and photophysical properties of three complexes containing the bridging ligand 5-(2-(4-pyridyl)ethyl)-2-(2-pyridyl)pyrimidine (pypm-py) are described. Two of the complexes are monometallic, ... -
Synthesis and photochemistry of Ru(II) complexes containing phenanthroline-based ligands with fused pyrrole rings
(American Chemical Society, 2002-12-16)Hydrolysis of 1,10-phenanthrolinopyrrole ethyl ester leads to the acid derivative which is unstable at room-temperature releasing CO(2) and forming 1,10-phenanthrolinopyrrole (php). The ligand reacts with ruthenium(II) to ... -
Synthesis and photoinduced electron transfer studies of a Tri(Phenothiazine)-subphthalocyanine-fullerene pentad
(American Chemical Society, 2013-09-06)A novel donor acceptor pentad featuring subphthalocyanine and fullerene as the primary electron donor and acceptor, and three phenothiazine entities as secondary hole transferring agents, have been newly synthesized and ... -
Synthesis and X-ray crystal structures of mononuclear and multinuclear metal complexes of 3-substituted 4-cyanopyrazole ligands
(Elsevier Ltd, 2023-10)Complexes of pyrazole ligands with a cyano substituent in the 4-position and alkyl or aryl substituents in the 3-position are reported, including mononuclear {M(HpzR,4CN)4X2 (X = Cl, M = Ni, R = t-Bu, c-Pr, Cy, Et; X = Cl, ... -
Synthesis and x-ray crystallographic characterization of [In(tsalen)(OAc)] (tsalen = N,N '-ethylenebis(thiosalicylideneimine))
(Elsevier Science Inc., 2016-08-16)The first synthesis and crystallographic characterization of a main-group metal complex of the N2S2 ligand N,N'-ethylenebis(thiosalicylideneimine) (tsalen) is reported, with the isolation and characterization of the ... -
Synthesis of urea picket porphyrins and their use in the elucidation of the role buried solvent plays in the selectivity and stoichiometry of anion binding receptors
(American Chemical Society, 2007-11-23)The synthesis of alpha,alpha-5,10-diurea and alpha,alpha,alpha-5,10,15-triurea picket porphyrins are detailed in this report. In previous reports, these porphyrins, along with alpha,alpha,alpha,alpha-5,10,15,20-tetraurea ... -
Synthesis, characterization, and application of antibody functionalized fluorescent silica nanoparticles
(Wiley-V C H Verlag GMBH, 2013-07-12)Fluorescent silica nanoparticles (FSNs) are prepared by incorporating dye into a mesoporous silica nanoparticle (MSN) synthesis procedure. FSNs containing sulforhodamine B, hydrophobically modified sulforhodamine B, and ... -
Synthesis, characterization, and photochemical and computational investigations of Ru(II) heterocyclic complexes containing 2,6-dimethylphenylisocyanide (CNx) ligand
(American Chemical Society, 2004-10-04)The isocyanide ligand forms complexes with ruthenium(II) bis-bipyridine of the type [Ru(bpy)(2)(CNx)Cl](CF(3)SO(3)) (1), [Ru(bpy)(2)(CNx)(py)](PF(6))(2) (2), and [Ru(bpy)(2)(CNx)(2)](PF(6))(2) (3) (bpy = 2,2'-bipyridine, ... -
Synthesis, characterization, photophysical, and computational studies of rhenium(I) tricarbonyl complexes containing the derivatives of bipyrazine
(American Chemical Society, 2007-08-06)The chloro and pyridinate derivatives of rhenium(I) tricarbonyl complexes containing the diimine ligands 2,2'-bipyrazine (bpz) and 5,5'-dimethyl-2,2'-bipyrazine (Me2bpz) are reported. Absorption maxima occur in the visible ... -
Synthesis, crystal and electronic structures, and nonlinear optical properties of Y$_4$Si$_3$S$_{12}$
(Wiley, 2022-03-21)A new acentric sulfide Y$_4$Si$_3$S$_{12}$ was grown by a high temperature vapor transport reaction. The crystal structure of Y$_4$Si$_3$S$_{12}$ was determined by single crystal X-ray diffraction. Y$_4$Si$_3$S$_{12}$ is ... -
Synthesis, crystal and electronic structures, nonlinear optical properties, and magnetic properties of two thiophosphates: KInP\(_2\)S\(_7\) and KCrP\(_2\)S\(_7\)
(MDPI, 2022-10-22)Two thiophosphates, KInP\(_2\)S\(_7\) and KCrP\(_2\)S\(_7\), were structurally characterized without investigating any optical properties. Herein in this work, KInP\(_2\)S\(_7\) and KCrP\(_2\)S\(_7\) were revisited to ... -
Synthesis, crystal growth, electronic properties and optical properties of $Y_6IV_{2.5}S_{14}$ (IV=Si, Ge)
(Wiley, 2021-12-06)Two isostructural ternary acentric sulfides, $Y_6Si_{2.5}S_{14}$ (1) and $Y_6Ge_{2.5}S_{14}$ (2) were re-investigated to understand the origin of the chemical flexibility of $RE_6B_xC_yCh_{14}$(RE=Y, La−Lu; B=Si, Ge, Sn, ... -
Synthesis, crystal structure, and thermoelectric properties of ternary phosphide $BaCu_5P_3$
(Elsevier, 2021-04)A new copper-phosphide, $BaCu_5P_3$ was synthesized by a high-temperature solid-state route and salt flux method. The crystal structure of $BaCu_5P_3$ was determined using single crystal X-ray diffraction. $BaCu_5P_3$ ... -
Synthesis, crystal structure, linear and nonlinear optical properties of quaternary sulfides $Ba_6$$(Cu_2X)$$Ge_4$$S_{16}$ $(X=Mg, Mn, Cd)$
(Elsevier, 2021-08-01)Three new quaternary noncentrosymmetric sulfides, $Ba_6$$(Cu_{1.9}$$4Mg_{1.1})$$Ge_4$$S_{16,}$ $Ba_6$$(Cu_{2.2}$$Mn_{0.8})$$Ge_4$$S_{16,}$ and $Ba_6$($Cu_{1.6}$$Cd_{1.4}$)$Ge_4$$S_{16,}$ have been synthesized by a ... -
Synthesis, crystal structures and magnetic properties of tricyanomethanide-containing copper(II) complexes
(RSC Publishing, 2008-03-28)The preparation, crystal structures and magnetic properties of the copper(II) complexes of formula [Cu(pyim)(tcm)2]n (1), [Cu(bpy)(tcm)2]n (2), [Cu4(bpz)4(tcm)8] (3), {[Cu(terpy)(tcm)]·tcm}n (4) and {[Cu2(tppz)(tcm)4]·3/2H2O}n ...