Browsing Chemistry and Biochemistry by Title
Now showing items 649-668 of 675
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To keep or not to keep? the question of crystallographic waters for enzyme simulations in organic solvent
(Taylor & Francis Group, 2016)The use of enzymes in non-aqueous solvents expands the use of biocatalysts to hydrophobic substrates, with the ability to tune selectivity of reactions through solvent selection. Non-aqueous enzymology also allows for ... -
Top-down ion mobility separations of isomeric proteoforms
(American Chemical Society, 2022-12-23)Continuing advances in proteomics highlight the ubiquity and biological importance of proteoforms proteins with varied sequence, splicing, or distribution of post-translational modifications (PTMs). The preeminent example ... -
Transport of tryptophan into SH-SY5Y neuronal cells
(Wichita State University. Graduate School., 2008-04-25)The human neuroblastoma cell line SH-SY5Y is a commonly used catecholaminergic model in studies related to neurotoxicity of various substances, oxidative stress, and neurodegenerative diseases. Specific transport of ... -
Tridentate N(2)S ligand from 2,2'-dithiodibenzaldehyde and N,N-dimethylethylenediamine: synthesis, structure, and characterization of a Ni(II) complex with relevance to Ni Superoxide Dismutase
(Elsevier, 2011-07-15)Nickel Superoxide Dismutase (NiSOD) and the A-cluster of Carbon Monoxide Dehydrogenase/Acetyl Coenzyme A Synthase (CODH/ACS) both feature active sites with Ni coordinated by thiolate and amide donors. It is likely that the ... -
Tuning cationic micelle properties with an antioxidant additive: A molecular perspective
(American Chemical Society, 2021-04-01)In this work, we characterize the micellization and morphology transition induced in aqueous cetyltrimethylammonium bromide (CTAB) solution by the addition of the antioxidant propyl gallate (PG) using tensiometry, rheology, ... -
Two similar dibenzo cyclic ethers with dissimilar conformations
(Wiley-Blackwell, 2009-01-01)Two dibenzo cyclic ether compounds, 6,12-dibromodibenzo[d,i]-1,2,3,6,7,8-hexahydro-1,3-dioxecin (systematic name: 8,16-dibromo-2,4-dioxatricyclo[12.4.0.0(5,10)]octadeca-5,7,9,14,16,18-hexaene), C(16)H(14)Br(2)O(2), (II), ... -
Two-component polymer films of palladium and fullerene with covalently linked crown ether voids: effect of cation binding on the redox behavior
(Springer, 2012-01)Redox active films have been generated via electrochemical reduction in a solution containing palladium(II) acetate and fulleropyrrolidine with covalently linked crown ethers, viz., benzo-15-crown-5 and benzo-18-crown-6. ... -
Ultrafast photoinduced energy and electron transfer in multi-modular donor-acceptor conjugates
(Wiley-Blackwell, 2012-10)New multi-modular donoracceptor conjugates featuring zinc porphyrin (ZnP), catechol-chelated boron dipyrrin (BDP), triphenylamine (TPA) and fullerene (C60), or naphthalenediimide (NDI) have been newly designed and synthesized ... -
Ultrafast singlet-singlet energy transfer in self-assembled via metal-ligand axial coordination of free-base porphyrin-zinc phthalocyanine and free-base porphyrin-zinc naphthalocyanine dyads
(American Chemical Society, 2010-01-14)Singlet-singlet energy transfer in self-assembled via axial coordination of imidazole-appended (at different positions of one of the meso-phenyl entities) free-base tetraphenylporphyrin, H(2)PIm, to either zinc phthalocyanine, ... -
Ultrahigh-resolution differential ion mobility separations of conformers for proteins above 10 kDa: onset of dipole alignment?
(American Chemical Society, 2014-11-04)Biomacromolecules tend to assume numerous structures in solution or the gas phase. It has been possible to resolve disparate conformational families but not unique geometries within each, and drastic peak broadening has ... -
Ultraviolet-curable cycloaliphatic polyesters containing spiroacetal moieties for application as powder coatings
(American Chemical Society, 2022-03-15)Thermosetting cycloaliphatic powder coatings that exhibit good weatherability, corrosion resistance, and mechanical properties have been desired for some time. Unfortunately, most cycloaliphatic resins have glass transition ... -
Uncover new reactivity of genetically encoded alkyl bromide non-canonical amino acids
(Frontiers Media S.A., 2022-02-18)Genetically encoded non-canonical amino acids (ncAAs) with electrophilic moieties are excellent tools to investigate protein-protein interactions (PPIs) both in vitro and in vivo. These ncAAs, including a series of alkyl ... -
Understanding fluorine chemical shifts and the molecular properties of organic molecules
(Wichita State University, 2018-05)Fluorinated molecules have emerged as important probes in drug design, and as strategies for enhancing protein stability and altering physicochemical properties of biological systems. Fluorine NMR plays a crucial role ... -
Urethane methacrylate reactive diluents for UV-curable polyester powder coatings
(Springer, 2021-01-15)Three urethane methacrylates, one monofunctional derivative and two di-functional derivatives with different chain lengths were used as reactive diluents in UV-curable polyester powder coatings. Each reactive diluent was ... -
Use of a high frequency oscillator to detect changes occuring in solids upon heating
(Wichita State University, 1951-05) -
Use of the 1,2,5-thiadiazolidin-3-one 1,1 dioxide and isothiazolidin-3-one 1,1 dioxide scaffolds in the design of potent inhibitors of serine proteinases
(Elsevier, 1998-03-03)The attachment of a phosphate leaving group to the 1,2,5-thiadiazolidin-3-one 1,1 dioxide and isothiazolidin-3-one 1,1 dioxide scaffolds was found to yield highly potent, time-dependent inhibitors of human leukocyte elastase ... -
Using ion mobility spectrometry to resolve isotopomers, identify isomers by isotopologic shifts, and predict mobility changes for post-translationally modified peptides
(Wichita State University, 2017-05)Differential or field asymmetric waveform ion mobility spectrometry (FAIMS) operating at high electric fields fully resolves isotopic isomers for a peptide with labeled residues. The naturally present isotopes, alone and ... -
Using surfactant-based colloidal systems to promote photoinduced synthesis of silver nanoparticles
(Wichita State University, 2018-07)This thesis focuses on the photo-initiated synthesis of silver nanoparticles in water with low concentration of stabilizing agents to investigate the role that surfactants, specifically their charge, plays in the synthesis. ... -
Utilization of the 1,2,3,5-thiatriazolidin-3-one 1,1-dioxide scaffold in the design of potential inhibitors of human neutrophil proteinase 3
(Elsevier, 2010-02-01)The S' subsites of human neutrophil proteinase 3 (Pr 3) were probed by constructing diverse libraries of compounds based on the 1,2,3,5-thiatriazolidin-3-one 1,1-dioxide using combinational and click chemistry methods. The ... -
Utilization of the 1,2,5-thiadiazolidin-3-one 1,1 dioxide scaffold in the design of potent inhibitors of serine proteases: SAR studies using carboxylates
(Elsevier, 2000-05-01)A series of carboxylate derivatives based on the 1,2,5-thiadiazolidin-3-one 1,1 dioxide and isothiazolidin-3-one 1,1 dioxide scaffolds has been synthesized and the inhibitory profile of these compounds toward human leukocyte ...