Show simple item record

dc.contributor.authorHales-Messenger, Stacey N.
dc.contributor.authorSwindle, Andrew L.
dc.date.accessioned2018-12-05T04:26:01Z
dc.date.available2018-12-05T04:26:01Z
dc.date.issued2018-10-01
dc.identifier.citationEnviron. Sci.: Processes Impacts, 2018,20, 1469-1478en_US
dc.identifier.issn2050-7887
dc.identifier.otherWOS:000447779700013
dc.identifier.urihttps://doi.org/10.1039/c8em00274f
dc.identifier.urihttp://hdl.handle.net/10057/15682
dc.descriptionClick on the DOI link to access the article (may not be free).en_US
dc.description.abstractChromate was used as a chemical probe to investigate the impact of mineral-organic contact time on the surface reactivity of two different sizes of goethite particles. A series of goethite-chromate sorption batch reactions were conducted in the presence and absence of Suwannee River humic acid (HA) and natural organic matter (NOM) using nano- and micro-scale goethite particles. In experiments with added organics the amount of time allowed for goethite-organic matter interaction (i.e. contact time) was varied from less than 1 minute, up to 24 hours prior to the addition of chromate. Results indicated that nano- and micro-scale goethite in the absence of organics sorbed nearly identical amounts of chromate on a per mass basis, despite the greater surface area of the smaller particles. Results also indicated that the presence of approximate to 10 mg L-1 of HA and a contact time of less than 1 minute reduced the amount of chromate sorbed by both nano- and micro-scale goethite. Increasing the contact time resulted in greater decreases in chromate sorption. Experiments using NOM produced similar results. While chromate sorption was most rapid during the first hour of the experiments, goethite particles continued to sorb additional chromate over a period of up to 7 days. Additionally, a noticeable impact on chromate sorption due to increased contact time was present over that time period.en_US
dc.description.sponsorshipInternal funding from Wichita State University.en_US
dc.language.isoen_USen_US
dc.publisherRoyal Society of Chemistryen_US
dc.relation.ispartofseriesEnvironmental Science: Processes & Impacts;v.20:no.10
dc.subjectAtomic-force microscopyen_US
dc.subjectHumic-substancesen_US
dc.subjectCarbon-tetrachlorideen_US
dc.subjectIron-oxideen_US
dc.subjectDesorption-kineticsen_US
dc.subjectMolecular-structureen_US
dc.subjectAquatic colloidsen_US
dc.subjectAqueous-solutionen_US
dc.subjectNatural-watersen_US
dc.subjectParticle-sizeen_US
dc.titleUsing chromate to investigate the impact of mineral-organic contact time on the surface reactivity of goethiteen_US
dc.typeArticleen_US
dc.rights.holder© Royal Society of Chemistry 2018en_US


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record