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dc.contributor.authorSenaratne, Nilmini K.
dc.contributor.authorMwania, Tom M.
dc.contributor.authorMoore, Curtis E.
dc.contributor.authorEichhorn, David M.
dc.date.accessioned2018-04-22T20:29:59Z
dc.date.available2018-04-22T20:29:59Z
dc.date.issued2018-05-01
dc.identifier.citationSenaratne, Nilmini K.; Mwania, Tom M.; Moore, Curtis E.; Eichhorn, David M. 2018. Ni complexes of N2S ligands with amine/imine and amine/amide donors with relevance to the active site of Ni superoxide dismutase. Inorganica Chimica Acta, vol. 476:pp 27-37en_US
dc.identifier.issn0020-1693
dc.identifier.otherWOS:000428436900005
dc.identifier.urihttps://doi.org/10.1016/j.ica.2018.02.006
dc.identifier.urihttp://hdl.handle.net/10057/14947
dc.descriptionClick on the DOI link to access the article (may not be free).en_US
dc.description.abstractA series of Ni complexes of the form [Ni((NNS)-S-Im)(RS)] ((NNS)-S-Im = (2-(N-(dimethylaminoethyl)iminomethyl) benzenethiolate; R = phenyl, 4-nitrophenyl, 4-fluorophenyl, 4-chlorophenyl, 4-t-butylphenyl, t-butyl), as well as two complexes of the form [Ni((NNS)-S-Am)(RS)] ((NNS)-S-Am = 2-(N-(dimethylaminoethyl) aminocarbonyl) benzenethiolate; R = phenyl, 4-nitrophenyl) have been synthesized using 2,2'-dithiodibenzaldehyde and 2,2'-dithiodibenzoylchloride, respectively, as synthons for introducing the thiolate into the tridentate ligands. The two ligands and series of complexes feature the N2S2 coordination environment found at the active site of Ni superoxide dismutase and differ only in the identity of one of the N donors (imine vs. amide). Those with the amide N donor contain the exact donor set present in reduced Ni superoxide dismutase. The complexes have been characterized by X-ray crystallography, electronic spectroscopy, and electrochemistry.en_US
dc.description.sponsorshipWSU Regional Institute on Aging.en_US
dc.language.isoen_USen_US
dc.publisherElsevieren_US
dc.relation.ispartofseriesInorganica Chimica Acta;v.476
dc.subjectNickel complexen_US
dc.subjectAmide liganden_US
dc.subjectImine liganden_US
dc.subjectThiolate liganden_US
dc.subjectChelateen_US
dc.titleNi complexes of N2S ligands with amine/imine and amine/amide donors with relevance to the active site of Ni superoxide dismutaseen_US
dc.typeArticleen_US
dc.rights.holder© 2018 Elsevier B.V. All rights reserved.en_US


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