dc.contributor.author | Sullivan, Michael T. | |
dc.contributor.author | Senaratne, Nilmini K. | |
dc.contributor.author | Eichhorn, David M. | |
dc.date.accessioned | 2016-08-07T23:08:35Z | |
dc.date.available | 2016-08-07T23:08:35Z | |
dc.date.issued | 2016-08-16 | |
dc.identifier.citation | Sullivan, Michael T.; Senaratne, Nilmini K.; Eichhorn, David M. 2016. Synthesis and x-ray crystallographic characterization of [In(tsalen)(OAc)] (tsalen = N,N '-ethylenebis(thiosalicylideneimine)). Polyhedron, vol. 114, 16 August 2016:pp 152–155 | en_US |
dc.identifier.issn | 0277-5387 | |
dc.identifier.other | WOS:000379564400022 | |
dc.identifier.uri | http://dx.doi.org/10.1016/j.poly.2015.11.026 | |
dc.identifier.uri | http://hdl.handle.net/10057/12315 | |
dc.description | Click on the DOI link to access the article (may not be free). | en_US |
dc.description.abstract | The first synthesis and crystallographic characterization of a main-group metal complex of the N2S2 ligand N,N'-ethylenebis(thiosalicylideneimine) (tsalen) is reported, with the isolation and characterization of the indium(III) compound [In(tsalen)(OAc)]. This compound has been crystallographically characterized and is shown to have a distorted trigonal bipyramidal geometry with a ligand that is unusually distorted from planarity. A byproduct of the synthesis, [In(en)(2)(OAc)(2)](OAc), has also been isolated and characterized. | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | Elsevier Science Inc. | en_US |
dc.relation.ispartofseries | Polyhedron;v.114 | |
dc.subject | Indium complex | en_US |
dc.subject | Thiolate ligand | en_US |
dc.subject | Imine ligand | en_US |
dc.subject | Crystal structure | en_US |
dc.subject | Acetate ligand | en_US |
dc.title | Synthesis and x-ray crystallographic characterization of [In(tsalen)(OAc)] (tsalen = N,N '-ethylenebis(thiosalicylideneimine)) | en_US |
dc.type | Article | en_US |
dc.rights.holder | © 2015 Elsevier Ltd. All rights reserved. | en_US |