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dc.contributor.authorSullivan, Michael T.
dc.contributor.authorSenaratne, Nilmini K.
dc.contributor.authorEichhorn, David M.
dc.identifier.citationSullivan, Michael T.; Senaratne, Nilmini K.; Eichhorn, David M. 2016. Synthesis and x-ray crystallographic characterization of [In(tsalen)(OAc)] (tsalen = N,N '-ethylenebis(thiosalicylideneimine)). Polyhedron, vol. 114, 16 August 2016:pp 152–155en_US
dc.descriptionClick on the DOI link to access the article (may not be free).en_US
dc.description.abstractThe first synthesis and crystallographic characterization of a main-group metal complex of the N2S2 ligand N,N'-ethylenebis(thiosalicylideneimine) (tsalen) is reported, with the isolation and characterization of the indium(III) compound [In(tsalen)(OAc)]. This compound has been crystallographically characterized and is shown to have a distorted trigonal bipyramidal geometry with a ligand that is unusually distorted from planarity. A byproduct of the synthesis, [In(en)(2)(OAc)(2)](OAc), has also been isolated and characterized.en_US
dc.publisherElsevier Science Inc.en_US
dc.subjectIndium complexen_US
dc.subjectThiolate liganden_US
dc.subjectImine liganden_US
dc.subjectCrystal structureen_US
dc.subjectAcetate liganden_US
dc.titleSynthesis and x-ray crystallographic characterization of [In(tsalen)(OAc)] (tsalen = N,N '-ethylenebis(thiosalicylideneimine))en_US
dc.rights.holder© 2015 Elsevier Ltd. All rights reserved.en_US

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