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dc.contributor.authorKadel, Lava R.
dc.contributor.authorBullinger, John R.
dc.contributor.authorBaum, Robert R.
dc.contributor.authorMoore, Curtis E.
dc.contributor.authorTierney, David L.
dc.contributor.authorEichhorn, David M.
dc.date.accessioned2016-08-01T00:31:53Z
dc.date.available2016-08-01T00:31:53Z
dc.date.issued2016-06
dc.identifier.citationKadel, Lava R.; Bullinger, John R.; Baum, Robert R.; Moore, Curtis E.; Tierney, David L.; Eichhorn, David M. 2016. Cyanoscorpionate ligands: agostic interactions in a series of metal complexes containing the Tris(4-cyano-3-phenylpyrazolyl)borate and Bis(4-cyano-3-phenylpyrazolyl)borate ligands. European Journal of Inorganic Chemistry Special Issue: The Significance of Scorpionate Ligands 50 Years On (Cluster Issue), Volume 2016, Issue 15-16, pages 2543–2551en_US
dc.identifier.issn1434-1948
dc.identifier.otherWOS:000378724700032
dc.identifier.urihttp://dx.doi.org/10.1002/ejic.201501268
dc.identifier.urihttp://hdl.handle.net/10057/12304
dc.descriptionClick on the DOI link to access the article (may not be free).en_US
dc.description.abstractScorpionate chemistry has long featured sandwich complexes with two trispyrazolylborate (Tp) or two bispyrazolylborate (Bp) ligands coordinated to a transition metal. Less common are complexes in which one Tp and one Bp ligand are coordinated to the metal. We report herein five such complexes of Ni-II, Mn-II, Co-II, or Fe-II involving Tp and Bp ligands comprising either 3-phenyl-4-cyanopyrazole or 3-phenylpyrazole, as well as a related Co-II complex with two Tp ligands, one of which is coordinated in a (2) fashion. All complexes feature an agostic interaction with a B-H hydrogen atom.en_US
dc.description.sponsorshipNational Science Foundation (NSF) (CHE-1152755) to D. L. T.en_US
dc.language.isoen_USen_US
dc.publisherWiley Periodicals, Inc.en_US
dc.relation.ispartofseriesEuropean Journal of Inorganic Chemistry;v.2016:no.15-16
dc.subjectAgostic interactionsen_US
dc.subjectN ligandsen_US
dc.subjectTridentate ligandsen_US
dc.subjectScorpionate ligandsen_US
dc.subjectTransition metalsen_US
dc.titleCyanoscorpionate ligands: agostic interactions in a series of metal complexes containing the Tris(4-cyano-3-phenylpyrazolyl)borate and Bis(4-cyano-3-phenylpyrazolyl)borate ligandsen_US
dc.typeArticleen_US
dc.rights.holder© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheimen_US


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