dc.contributor.advisor | Rillema, D. Paul | |
dc.contributor.author | Oweggi, Eric | |
dc.date.accessioned | 2014-10-13T17:04:57Z | |
dc.date.available | 2014-10-13T17:04:57Z | |
dc.date.issued | 2014-04-25 | |
dc.identifier.citation | Oweggi, Eric. 2014. Photocatalytic Conversion of CO2 to CO and its Study in the Production of Acrylic Acid. --In Proceedings: 10th Annual Symposium on Graduate Research and Scholarly Projects. Wichita, Ks: Wichita State University, p. 137 | |
dc.identifier.uri | http://hdl.handle.net/10057/10823 | |
dc.description | Presented to the 10th Annual Symposium on Graduate Research and Scholarly Projects (GRASP) held at the Heskett Center, Wichita State University, April 25, 2014. | |
dc.description | Research completed at Department of Chemistry, College of Liberal Arts and Sciences | |
dc.description.abstract | The synthesis of various Rhenium complexes is followed by an investigation of their capacity to reduce CO2 photocatalytically. Re(bpy)(CO)3X (X=Cl, NCS) is irradiated in a CO2 saturated DMF:TEOA solution in a Pyrex tube capped with a serum cap. The CO produced in the reaction is tracked using a gas chromatograph, and this is followed by examining the carboxylated Re(dcbpy)(CO)3X dye derivatives in the same manner. The objective is attaching the Rhenium dye to TiO2 making it a photocathode and replacing the sacrificial reagent, TEOA, with a photoanode in a photo-electrochemical cell which would produce both electricity and carry out a catalytic reaction simultaneously. CO2 Insertion into olefin-metal bonds is also studied for the production of acrylic acid | |
dc.description.sponsorship | Graduate School, Academic Affairs, University Libraries | |
dc.language.iso | en_US | |
dc.publisher | Wichita State University. Graduate School | |
dc.relation.ispartofseries | GRASP | |
dc.relation.ispartofseries | v.10 | |
dc.title | Photocatalytic conversion of CO2 to CO and its study in the production of acrylic acid | |
dc.type | Conference paper | |
dc.rights.holder | Wichita State University | |