Altering the reaction pathways of aminopyridine with 4,5-diazafluorenone: Metal ion control
Wang, Youxiang Rillema, D. Paul
Wang, Youxiang
Rillema, D. Paul
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1997-09-22
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Youxiang Wang, D.Paul Rillema, Altering the Reaction Pathways of Aminopyridine With 4,5-Diazafluorenone : Metal Ion Control, Tetrahedron Letters, Volume 38, Issue 38, 1997, Pages 6627-6630, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(97)01535-9.
Abstract
A parallel study of the ligand 4,5-diazafluorenone reactivity in the presence and absence of ruthenium(II) ion revealed that the reaction pathway of the ligand 4,5-diazafluoren-9-one with aminopyridine can be altered from the normal Schiff-base reaction to an unusual ring opening reaction upon its coordination to ruthenium(II) ion.
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Elsevier
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Tetrahedron Letters
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00404039