Cyanoscorpionate ligands: agostic interactions in a series of metal complexes containing the Tris(4-cyano-3-phenylpyrazolyl)borate and Bis(4-cyano-3-phenylpyrazolyl)borate ligands
Kadel, Lava R. Bullinger, John R. Baum, Robert R. Moore, Curtis E. Tierney, David L. Eichhorn, David M.
Kadel, Lava R.
Bullinger, John R.
Baum, Robert R.
Moore, Curtis E.
Tierney, David L.
Eichhorn, David M.
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2016-06
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Article
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Agostic interactions,N ligands,Tridentate ligands,Scorpionate ligands,Transition metals
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Kadel, Lava R.; Bullinger, John R.; Baum, Robert R.; Moore, Curtis E.; Tierney, David L.; Eichhorn, David M. 2016. Cyanoscorpionate ligands: agostic interactions in a series of metal complexes containing the Tris(4-cyano-3-phenylpyrazolyl)borate and Bis(4-cyano-3-phenylpyrazolyl)borate ligands. European Journal of Inorganic Chemistry Special Issue: The Significance of Scorpionate Ligands 50 Years On (Cluster Issue), Volume 2016, Issue 15-16, pages 2543–2551
Abstract
Scorpionate chemistry has long featured sandwich complexes with two trispyrazolylborate (Tp) or two bispyrazolylborate (Bp) ligands coordinated to a transition metal. Less common are complexes in which one Tp and one Bp ligand are coordinated to the metal. We report herein five such complexes of Ni-II, Mn-II, Co-II, or Fe-II involving Tp and Bp ligands comprising either 3-phenyl-4-cyanopyrazole or 3-phenylpyrazole, as well as a related Co-II complex with two Tp ligands, one of which is coordinated in a (2) fashion. All complexes feature an agostic interaction with a B-H hydrogen atom.
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Wiley Periodicals, Inc.
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European Journal of Inorganic Chemistry;v.2016:no.15-16
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1434-1948