Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate
Oshin, Kayode Landis, Arthur M. Smucker, Bradley W. Eichhorn, David M. Rillema, D. Paul
Oshin, Kayode
Landis, Arthur M.
Smucker, Bradley W.
Eichhorn, David M.
Rillema, D. Paul
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2004
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Article
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Organic compounds,Hydrogen bonds
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Citation
Oshin, K., Landis, A. M., Smucker, B. W., Eichhorn, D. M. & Rillema, D. P. (2004). fac-BipyridylÂtriÂcarbonylÂ(pyridine)Ârhenium(I) triÂfluoroÂmethaneÂsulfonate. Acta Cryst. E60, m1126â m1127.
Abstract
The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.
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International Union of Crystallography
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Acta Crystallographica Section E: Structure Reports Online
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16005368