| dc.contributor |
Wichita State University. Department of Chemistry |
en_US |
| dc.contributor.author |
Zhao, Ningfeng |
en_US |
| dc.contributor.author |
Van Stipdonk, Michael J. |
en_US |
| dc.contributor.author |
Bauer, Cary |
en_US |
| dc.contributor.author |
Campana, Charles |
en_US |
| dc.contributor.author |
Eichhorn, David M. |
en_US |
| dc.date.accessioned |
2012-02-06T17:16:27Z |
|
| dc.date.available |
2012-02-06T17:16:27Z |
|
| dc.date.issued |
2007-10-15 |
en_US |
| dc.identifier |
17845029 |
en_US |
| dc.identifier |
0366543 |
en_US |
| dc.identifier.citation |
Inorganic chemistry. 2007 Oct 15; 46(21): 8662-7. |
en_US |
| dc.identifier.issn |
0020-1669 |
en_US |
| dc.identifier.uri |
http://dx.doi.org/10.1021/ic700628b |
en_US |
| dc.identifier.uri |
http://hdl.handle.net/10057/4325 |
|
| dc.description |
Click on the DOI link below to access the article. |
en_US |
| dc.description.abstract |
Reaction of the new cyanoscorpionate ligand, hydrotris(4-cyano-3-phenyl)pyrazolylborate (Tp(Ph),(4CN)) with Co(II), Mn(II), and Fe(II) unexpectedly results in the isolation only of crystals containing sandwich complexes in which the ligands have been isomerized to produce the heterocyanoscorpionate hydrobis(4-cyano-3-phenylpyrazolyl)(4-cyano-5-phenylpyrazolyl)borate (Tp(Ph),(4CN*)). The three complexes have been characterized crystallographically and are isostructural, with each ligand acting in a tridentate manner toward the metal. The isomerization of the ligand appears to be more facile than that of the analogous non-cyano ligand, Tp(Ph), with which crystals of the unisomerized sandwich compound have been isolated for Mn(II) and Fe(II). |
en_US |
| dc.format.extent |
8662-7 |
en_US |
| dc.language.iso |
eng |
en_US |
| dc.publisher |
American Chemical Society |
en_US |
| dc.relation.ispartofseries |
Inorganic chemistry |
en_US |
| dc.relation.ispartofseries |
Inorg Chem |
en_US |
| dc.source |
NLM |
en_US |
| dc.title |
Sandwich compounds of cyanotrispyrazolylborates: complexation-induced ligand isomerization |
en_US |
| dc.type |
Article |
en_US |
| dc.coverage.spacial |
United States |
en_US |
| dc.description.version |
peer reviewed |
en_US |
| dc.rights.holder |
Copyright © 2007 American Chemical Society |
en_US |