| dc.contributor |
Wichita State University. Department of Chemistry |
en_US |
| dc.contributor.author |
Casalboni, Fiorella |
en_US |
| dc.contributor.author |
Mulazzani, Quinto G. |
en_US |
| dc.contributor.author |
Clark, Catherine D. |
en_US |
| dc.contributor.author |
Hoffman, Morton Z. |
en_US |
| dc.contributor.author |
Orizondo, Peter L. |
en_US |
| dc.contributor.author |
Perkovic, Marc W. |
en_US |
| dc.contributor.author |
Rillema, D. Paul |
en_US |
| dc.date.accessioned |
2012-02-06T17:15:38Z |
|
| dc.date.available |
2012-02-06T17:15:38Z |
|
| dc.date.issued |
1997-05-21 |
en_US |
| dc.identifier |
11669858 |
en_US |
| dc.identifier |
0366543 |
en_US |
| dc.identifier |
ic960657e |
en_US |
| dc.identifier.citation |
Inorganic chemistry. 1997 May 21; 36(11): 2252-2257. |
en_US |
| dc.identifier.issn |
1520-510X |
en_US |
| dc.identifier.issn |
0020-1669 |
en_US |
| dc.identifier.uri |
http://hdl.handle.net/10057/4245 |
|
| dc.description |
Full text of this article is not available in SOAR. |
en_US |
| dc.description.abstract |
The acid-base and electrochemical properties of the MLCT excited states and the one-electron-reduced forms of the three Ru(bpy)(3)(-)()(p)()(pypm)(p)()(2+) complexes, where bpy = 2,2'-bipyridine, pypm = 2-(2'-pyridyl)pyrimidine, and p = 1-3, have been examined in aqueous solution; a determination has been made of the ground- and excited-state electrochemical potentials, the values of the pK(a) and deprotonation rate constants of the conjugate acids of the excited states and the one-electron-reduced complexes, and the kinetics of the second-order decays of the reduced species. Comparison is made with the behavior of the analogous 10 complexes of the form Ru(bpy)(3)(-)()(m)()(-)()(z)()(bpm)(m)()(bpz)(z)()(2+), where bpm = 2,2'-bipyrimidine, bpz = 2,2'-bipyrazine, m and z = 0-3, and m + z </= 3, which have been studied in detail before. |
en_US |
| dc.format.extent |
2252-2257 |
en_US |
| dc.language.iso |
eng |
en_US |
| dc.publisher |
American Chemical Society |
en_US |
| dc.relation.ispartofseries |
Inorganic chemistry |
en_US |
| dc.relation.ispartofseries |
Inorg Chem |
en_US |
| dc.source |
NLM |
en_US |
| dc.title |
Acid-Base and Electrochemical Properties of the MLCT Excited States and One-Electron-Reduced Forms of Ruthenium(II) Complexes Containing 2-(2'-Pyridyl)pyrimidine and 2,2'-Bipyridine in Aqueous Solution |
en_US |
| dc.type |
Article |
en_US |
| dc.description.version |
peer reviewed |
en_US |
| dc.rights.holder |
Copyright © 1997 American Chemical Society |
en_US |